Dow and Evonik Partner to Improve Propylene Glycol Production

Propylene glycol, used as a de-icing agent
The technology partnership aims to efficiently produce propylene glycol, which is used in the production of polyester resins and as a de-icing agent.

Dow and Evonik have entered into an exclusive technology partnership to use a method for directly synthesizing propylene glycol (PG) from propylene and hydrogen, according to an Evonik press release. The release states that the new process conserves resources and reduces investment costs. The pilot plant for the partnership will be located at Evonik’s Hanau site.

The basis for the technology, named HYPROSYN™, has been created over the last few years by a team of over 100 Evonik employees. The key element is a catalytic system developed by Evonik researchers that allows for direct synthesis of PG from propylene and hydrogen peroxide, in a process offering high yield and comparatively low energy consumption.

“We are very pleased to be cooperating with Dow to bring the HYPROSYN™ process to market maturity,” said Michael Träxler, the head of Evonik’s Active Oxygens business line, in the company release. “Dow is by far the largest producer of PG worldwide and a world leader in the field of material science. Dow’s technical and market experience will be invaluable in the scale up of our development.”

According to the press release some 1.9 million metric tons of propylene glycol were used worldwide in 2018. The molecule is used in the production of polyester resins and as a de-icing agent. It is also an important food additive and serves as a humectant and co-surfactant in many products in the home and personal care market.

A pilot plant is to be constructed in Hanau by the end of 2020, with large-scale technical implementation to follow a few years later. “We believe that the new HYPROSYN™ direct synthesis technology will enable a more competitive route to produce PG with an improved environmental profile, providing us greater flexibility in serving our customers,” said Andrew Jones, global business director for Propylene Oxide, Propylene Glycol, Chlor-Alkali and Vinyl at Dow in the Evonik press release.

In the traditional process propylene oxide (PO) is converted to PG using water. The HYPROSYN™ technology offers several advantages over that process:

  • It is expected to consume significantly less energy while providing a higher yield.
  • The HYPROSYN™ process combines all reaction steps in a single reactor, eliminating the need for investment in additional PO capacity.
  • Existing PG plants can be retrofitted with little effort.
  • Only hydrogen peroxide and propylene are processed as feedstock, increasing flexibility and lowering total investment cost.

“In addition to potential license revenue, this partnership also demonstrates how we create new areas of application for hydrogen peroxide and positions us as a preferred provider,” said Träxler. According to the release, the molecule has become established as an important oxidizing agent for chemical synthesis – not least as a result of the HPPO process for the production of propylene
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“We are pleased to work together with Evonik to bring this sustainable and innovative new technology to market,” said Jones in the press release. “We believe it is an important development in support of growing demand from our PG customers worldwide.”

 

 

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